Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes.
نویسندگان
چکیده
A dysprosium(iii) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 32 شماره
صفحات -
تاریخ انتشار 2014